Contemporaneously, this mechanism was recognized by others, and a model study was reported (see Peroxycyclization Model Study) in which one-electron oxidation of an allylic hydroperoxide produces ...

More information: Honggang Zhang et al, Site- and enantioselective allylic and propargylic C–H oxidation enabled by copper-based biomimetic catalysis, Nature Catalysis (2025). DOI: 10.1038 ...