Carbonyl-olefin metathesis (COM) reactions are a fascinating area of synthetic organic chemistry that involve the exchange of carbonyl and olefin groups to form new carbon-carbon double bonds.
The 12,13-epoxy-9-hydroperoxide is a known product from the reaction of 13-HPODE and iron or hydrolysis of the methyl ... peroxycyclization to generate a dioxetane intermediate that fragments to ...
Foods which contain edible oils will spoil once exposed to oxygen from the air due to oxidation reactions ... forming two additional ketone (carbonyl) groups. The loss of hydrogen indicates ...
Researchers at Leipzig University have developed a new process for reversing the polarity of chemical compounds, also known as umpolung, for the precise synthesis of pharmaceuticals. This innovative ...
Researchers at Leipzig University have developed a new process for reversing the polarity of chemical compounds, also known as umpolung, for the precise synthesis of pharmaceuticals.
H-abstraction from the –CH x group, which formed carbonyl oxides, was favorable for HO-RO 2 radicals. For the reactions HO-RO 2 · + HO-RO·, the dominant pathway was the barrierless formation ...