The direct reaction of triplet oxygen with a singlet organic molecule would violate a fundamental principle of physics, the conservation of angular momentum, and thus is 'spin-forbidden'.

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One exception is the oxygen evolution reaction (OER) where strongly correlated metals and oxides are used as catalysts. In OER, spin alignment facilitates the transition of singlet state of the ...

We have been exploring reactions of singlet oxygen with heteroatoms such as phosphorus and sulfur and the interaction ... It is important to understand the nature of such reactive intermediates ...